Abstract

The aging of asphalt concrete is mainly governed by the aging of the asphalt binder, which is a naturally occurring organic hydrocarbon. Both chemical and rheological properties of asphalt binder are expected to change as aging continues. The pavement industry is increasing the use of different recycled materials in the construction and rehabilitation of flexible pavements to preserve natural resources, save costs, and reduce environmental emissions. The aged binder from recycled materials is expected to alter the binder properties and its aging characteristics in the new mix. In this study, 3 different virgin base binder types (PG 64-16, PG 58-22, and PG 70-10) and 7 different binder blends containing recycled binders (up to 100 % binder replacement) were subjected to different aging conditions. The rheological and chemical properties of these binders were characterized using a dynamic shear rheometer and Fourier transform infrared spectroscopy, respectively. It was found that the Glover-Rowe parameter distinctively captured the change in binder rheological properties with aging for the different binder blends. A good correlation (R2 value of 0.83–1.00) was observed between binder chemical and rheological properties. The source and performance grade of the base binder were found to govern the correlation between the rheological and chemical properties of the blended binder. Hamburg wheel tracking (for rutting and moisture sensitivity) and indirect tensile asphalt cracking test (for fracture) tests were conducted on asphalt mixes maintaining the same blended binder ratios. The laboratory mix performance parameters were found to correlate well with the properties of the blended binders. Therefore, properties of the blended binders can be an important source of information for predicting the performance of asphalt mixes containing recycled materials.

References

1.
Liang
Y.
,
Wu
R.
,
Harvey
J. T.
,
Jones
D.
, and
Alavi
M. Z.
, “
Investigation into the Oxidative Aging of Asphalt Binders
,”
Transportation Research Record
2673
, no. 
6
(June
2019
):
368
378
, https://doi.org/10.1177/0361198119843096
2.
Zhu
Z.
,
Singhvi
P.
,
Ali
U. M.
,
Ozer
H.
, and
Al-Qadi
I. L.
, “
Quantification of the Effect of Binder Source on Flexibility of Long-Term Aged Asphalt Concrete
,”
Transportation Research Record
2674
, no. 
9
(September
2020
):
605
616
, https://doi.org/10.1177/0361198120930717
3.
Harvey
J.
and
Tsai
B.-W.
, “
Long-Term Oven-Aging Effects on Fatigue and Initial Stiffness of Asphalt Concrete
,”
Transportation Research Record
1590
, no. 
1
(January
1997
):
89
98
, https://doi.org/10.3141/1590-11
4.
Rahman
M. A.
,
Ghabchi
R.
,
Zaman
M.
, and
Ali
S. A.
, “
Rutting and Moisture-Induced Damage Potential of Foamed Warm Mix Asphalt (WMA) Containing RAP
,”
Innovative Infrastructure Solutions
6
, no. 
3
(
2021
): 158, https://doi.org/10.1007/s41062-021-00528-7
5.
Guo
N.
,
You
Z.
,
Zhao
Y.
,
Tan
Y.
, and
Diab
A.
, “
Laboratory Performance of Warm Mix Asphalt Containing Recycled Asphalt Mixtures
,”
Construction and Building Materials
64
(August
2014
):
141
149
, https://doi.org/10.1016/j.conbuildmat.2014.04.002
6.
Dong
F.
,
Yu
X.
,
Xu
B.
, and
Wang
T.
, “
Comparison of High Temperature Performance and Microstructure for Foamed WMA and HMA with RAP Binder
,”
Construction and Building Materials
134
(March
2017
):
594
601
, https://doi.org/10.1016/j.conbuildmat.2016.12.106
7.
Al-Qadi
I. L.
,
Ozer
H.
,
Zhu
Z.
,
Singhvi
P.
,
Mohamed Ali
U.
,
Sawalha
M.
,
Espinoza Luque
A. F.
,
García Mainieri
J. J.
, and
Zehr
T. G.
,
Development of Long-Term Aging Protocol for Implementation of the Illinois Flexibility Index Test (I-FIT), Research Report No. FHWA-ICT-19-009
(
Urbana, IL
:
Illinois Center for Transportation
,
2019
).
8.
Harvey
J.
,
Chong
A.
, and
Roesler
J.
,
Climate Regions for Mechanistic-Empirical Pavement Design in California and Expected Effects on Performance
(
Sacramento, CA
:
California Department of Transportation
,
2000
).
9.
Rahman
M. A.
,
Zaman
M.
,
Ali
S. A.
,
Ghabchi
R.
, and
Ghos
S.
, “
Evaluation of Mix Design Volumetrics and Cracking Potential of Foamed Warm Mix Asphalt (WMA) Containing Reclaimed Asphalt Pavement (RAP)
,”
International Journal of Pavement Engineering
23
, no. 
10
(
2022
):
3454
3466
, https://doi.org/10.1080/10298436.2021.1902522
10.
Al-Qadi
I. L.
,
Ozer
H.
,
Lambros
J.
,
El Khatib
A.
,
Singhvi
P.
,
Khan
T.
,
Rivera-Perez
J.
, and
Doll
B.
,
Testing Protocols to Ensure Performance of High Asphalt Binder Replacement Mixes Using RAP and RAS, Research Report No. FHWA-ICT-15-017
(
Urbana, IL
:
Illinois Center for Transportation
,
2015
).
11.
Newcomb
D. E.
and
Epps
J. A.
,
Asphalt Recycling Technology: Literature Review and Research Plan, ESL-TR-81-42
(
Tyndall Air Force Base, FL
:
Air Force Engineering and Services Center
,
1981
).
12.
Williams
B. A.
,
Willis
J. R.
, and
Shacat
J.
,
Asphalt Pavement Industry Survey on Recycled Materials and Warm-Mix Asphalt Usage: 2019
(
Greenbelt, MD
:
National Asphalt Pavement Association
,
2019
).
13.
Zhou
Z.
,
Gu
X.
,
Dong
Q.
,
Ni
F.
, and
Jiang
Y.
, “
Investigation of the Oxidation Ageing of RAP Asphalt Blend Binders and Mixtures
,”
International Journal of Pavement Engineering
23
, no. 
3
(
2022
):
571
587
, https://doi.org/10.1080/10298436.2020.1763345
14.
Copeland
A.
,
D’Angelo
J.
,
Dongré
R.
,
Belagutti
S.
, and
Sholar
G.
, “
Field Evaluation of High Reclaimed Asphalt Pavement–Warm-Mix Asphalt Project in Florida: Case Study
,”
Transportation Research Record
2179
, no. 
1
(January
2010
):
93
101
, https://doi.org/10.3141/2179-11
15.
Harvey
J.
,
Monismith
C.
,
Horonjeff
R.
,
Bejarano
M.
,
Tsai
B.
, and
Kannekanti
V.
, “
Long-Life AC Pavements: A Discussion of Design and Construction Criteria Based on California Experience
,” in
International Symposium on Design and Construction of Long Lasting Asphalt Pavements: June 8-4, 2004, Auburn, Alabama
(
Auburn, AL
:
National Center for Asphalt Technology
,
2004
).
16.
Nunn
M.
, “
Long-Life Flexible Roads
,” in
Eighth International Conference on Asphalt Pavements
(
Seattle, WA
:
University of Washington, Seattle
,
1997
),
3
16
.
17.
Shu
X.
,
Huang
B.
, and
Vukosavljevic
D.
, “
Laboratory Evaluation of Fatigue Characteristics of Recycled Asphalt Mixture
,”
Construction and Building Materials
22
, no. 
7
(July
2008
):
1323
1330
, https://doi.org/10.1016/j.conbuildmat.2007.04.019
18.
Han
R.
,
Jin
X.
, and
Glover
C. J.
, “
Modeling Pavement Temperature for Use in Binder Oxidation Models and Pavement Performance Prediction
,”
Journal of Materials in Civil Engineering
23
, no. 
4
(April
2011
):
351
359
, https://doi.org/10.1061/(ASCE)MT.1943-5533.0000169
19.
Jin
X.
,
Cui
Y.
, and
Glover
C. J.
, “
Modeling Asphalt Oxidation in Pavement with Field Validation
,”
Petroleum Science and Technology
31
, no. 
13
(
2013
):
1398
1405
, https://doi.org/10.1080/10916466.2012.665115
20.
Glover
C. J.
,
Han
R.
,
Jin
X.
,
Prapaitrakul
N.
,
Cui
Y.
,
Rose
A.
,
Lawrence
J. J.
,
Padigala
M.
,
Arambula
E.
,
Park
E. S.
, and
Epps Martin
A.
,
Evaluation of Binder Aging and Its Influence in Aging of Hot Mix Asphalt Concrete: Technical Report
(
Austin, TX
:
Texas Department of Transportation
,
2014
).
21.
Bajaj
A.
,
Epps Martin
A.
,
King
G.
,
Glover
C.
,
Kaseer
F.
, and
Arámbula-Mercado
E.
, “
Evaluation and Classification of Recycling Agents for Asphalt Binders
,”
Construction & Building Materials
260
(November
2020
): 119864, https://doi.org/10.1016/j.conbuildmat.2020.119864
22.
Kim
Y. R.
,
Castorena
C.
,
Elwardany
M.
,
Rad
F. Y.
,
Underwood
S.
,
Akshay
G.
,
Gudipudi
P.
,
Farrar
M. J.
, and
Glaser
R. R.
,
Long-Term Aging of Asphalt Mixtures for Performance Testing and Prediction
(
Transportation Research Board
,
2018
).
23.
Zhang
Y.
,
Swiertz
D.
, and
Bahia
H. U.
, “
Use of Blended Binder Tests to Estimate Performance of Mixtures with High Reclaimed Asphalt Pavement/Recycled Asphalt Shingles Content
,”
Transportation Research Record
2675
, no. 
8
(August
2021
):
281
293
, https://doi.org/10.1177/0361198121997423
24.
Hofko
B.
,
Alavi
M. Z.
,
Grothe
H.
,
Jones
D.
, and
Harvey
J.
, “
Repeatability and Sensitivity of FTIR ATR Spectral Analysis Methods for Bituminous Binders
,”
Materials and Structures
50
, no. 
3
(
2017
): 187, https://doi.org/10.1617/s11527-017-1059-x
25.
Lamontagne
J.
,
Dumas
P.
,
Mouillet
V.
, and
Kister
J.
, “
Comparison by Fourier Transform Infrared (FTIR) Spectroscopy of Different Ageing Techniques: Application to Road Bitumens
,”
Fuel
80
, no. 
4
(March
2001
):
483
488
, https://doi.org/10.1016/S0016-2361(00)00121-6
26.
Williams
M. L.
,
Landel
R. F.
, and
Ferry
J. D.
, “
The Temperature Dependence of Relaxation Mechanisms in Amorphous Polymers and Other Glass-Forming Liquids
,”
Journal of the American Chemical Society
77
, no. 
14
(July
1955
):
3701
3707
, https://doi.org/10.1021/ja01619a008
27.
Yang
X.
and
You
Z.
, “
New Predictive Equations for Dynamic Modulus and Phase Angle Using a Nonlinear Least-Squares Regression Model
,”
Journal of Materials in Civil Engineering
27
, no. 
3
(March
2015
): 04014131, https://doi.org/10.1061/(ASCE)MT.1943-5533.0001070
28.
Shu
X.
,
Huang
B.
,
Shrum
E. D.
, and
Jia
X.
, “
Laboratory Evaluation of Moisture Susceptibility of Foamed Warm Mix Asphalt Containing High Percentages of RAP
,”
Construction and Building Materials
35
(October
2012
):
125
130
, https://doi.org/10.1016/j.conbuildmat.2012.02.095
29.
Hong
F.
,
Chen
D.-H.
, and
Mikhail
M. M.
, “
Long-Term Performance Evaluation of Recycled Asphalt Pavement Results from Texas: Pavement Studies Category 5 Sections from the Long-Term Pavement Performance Program
,”
Transportation Research Record
2180
, no. 
1
(January
2010
):
58
66
, https://doi.org/10.3141/2180-07
30.
Zhao
S.
,
Huang
B.
,
Shu
X.
,
Jia
X.
, and
Woods
M.
, “
Laboratory Performance Evaluation of Warm-Mix Asphalt Containing High Percentages of Reclaimed Asphalt Pavement
,”
Transportation Research Record
2294
, no. 
1
(January
2012
):
98
105
, https://doi.org/10.3141/2294-11
31.
Petersen
J. C.
,
Robertson
R. E.
,
Branthaver
J. F.
,
Harnsberger
P. M.
,
Duvall
J. J.
,
Kim
S. S.
,
Anderson
D. A.
,
Christiansen
D. W.
, and
Bahia
H. U.
,
Binder Characterization and Evaluation: Volume 1, SHRP-A-367
(
Washington, DC
:
Strategic Highway Research Program
,
1994
).
32.
Mensching
D. J.
,
Jacques
C. D.
, and
Daniel
J. S.
, “
Applying the Glover-Rowe Parameter to Evaluate Low-Temperature Performance of Hot Mix Asphalt LTPP Sections
,”
Journal of Materials in Civil Engineering
28
, no. 
10
(October
2016
): 04016096, https://doi.org/10.1061/(ASCE)MT.1943-5533.0001606
33.
Rowe
G.
, “
Prepared Discussion for the AAPT Paper by Anderson et al.: Evaluation of the Relationship between Asphalt Binder Properties and Non-load Related Cracking
,”
Electronic Journal of the Association of Asphalt Paving Technologists
80
(
2011
):
649
662
.
34.
Mensching
D. J.
,
Rowe
G. M.
,
Daniel
J. S.
, and
Bennert
T.
, “
Exploring Low-Temperature Performance in Black Space
,”
Road Materials and Pavement Design
16
, no. sup2 (
2015
):
230
253
, https://doi.org/10.1080/14680629.2015.1077015
35.
Rowe
G.
, “
Interrelationships in Rheological Parameters
,” in
51st Petersen Asphalt Research Conference
(
Laramie, WY
:
Western Research Institute
,
2014
).
36.
Glover
C. J.
,
Davison
R. R.
,
Domke
C. H.
,
Ruan
Y.
,
Juristyarini
P.
,
Knorr
D. B.
, and
Jung
S. H.
,
Development of a New Method for Assessing Asphalt Binder Durability with Field Validation, Report No. FHWA/TX-05/1872-2
(
Austin, TX
:
Texas Department of Transportation
,
2005
).
37.
Mogawer
W. S.
,
Booshehrian
A.
,
Vahidi
S.
, and
Austerman
A. J.
, “
Evaluating the Effect of Rejuvenators on the Degree of Blending and Performance of High RAP, RAS, and RAP/RAS Mixtures
,”
Road Materials and Pavement Design
14
, no. 
sup2
(
2013
):
193
213
, https://doi.org/10.1080/14680629.2013.812836
38.
Shen
J.
,
Huang
B.
, and
Hachiya
Y.
, “
Validation of Performance-Based Method for Determining Rejuvenator Content in HMA
,”
International Journal of Pavement Engineering
5
, no. 
2
(
2004
):
103
109
, https://doi.org/10.1080/10298430410001733509
39.
Zaumanis
M.
,
Mallick
R. B.
, and
Frank
R.
, “
Evaluation of Rejuvenator’s Effectiveness with Conventional Mix Testing for 100% Reclaimed Asphalt Pavement Mixtures
,”
Transportation Research Record
2370
, no. 
1
(January
2013
):
17
25
, https://doi.org/10.3141/2370-03
40.
Mogawer
W. S.
,
Austerman
A. J.
, and
Bonaquist
R.
, “
Using Space Diagrams to Evaluate the Effect of Softer Binder and Warm Mix Technologies in Reclaimed Asphalt Pavement Mixtures
,” in
TRB 95th Annual Meeting Compendium of Papers
(
Washington, DC
:
Transportation Research Board
,
2016
).
41.
He
Y.
,
Alavi
Z.
,
Harvey
J.
, and
Jones
D.
, “
Evaluating Diffusion and Aging Mechanisms in Blending of New and Age-Hardened Binders during Mixing and Paving
,”
Transportation Research Record
2574
, no. 
1
(January
2016
):
64
73
, https://doi.org/10.3141/2574-07
42.
Jiao
L.
,
Harvey
J. T.
,
Elkashef
M.
,
Liang
Y.
, and
Jones
D.
, “
Investigation of Surrogate Performance Related Tests for Fatigue Cracking of Asphalt Pavements
,”
Transportation Research Record
2675
, no. 
10
(October
2021
):
96
108
, https://doi.org/10.1177/03611981211010182
43.
Anderson
R. M.
,
King
G. N.
,
Hanson
D. I.
, and
Blankenship
P. B.
, “
Evaluation of the Relationship between Asphalt Binder Properties and Non-load Related Cracking
,”
Journal of the Association of Asphalt Paving Technologists
80
(
2011
):
615
664
.
This content is only available via PDF.
You do not currently have access to this content.