Abstract

A typical agricultural chemical spray process involves atomizing a liquid stream of diluted pesticide solution through hydraulic spray nozzles that inherently produce a wide spectrum of spray droplet sizes. Finer droplets have higher potential for off-target movement or drift, which is of concern due to its potential impact on neighboring crops and livestock, sensitive ecological resources, and human health. Research by the Spray Drift Task Force and others has demonstrated that, although spray nozzle selection and application parameters are the key factors to produce the desired droplet size spectrum, the physical properties of the spray solution have significant effects on the droplet size distribution for various kinds of nozzles. One of these properties of many spray fluids is the inclusion of an oil phase in the form of an emulsion. The effect of oil-in-water emulsions on the spray droplet size distribution has been demonstrated by previous work. However, the mechanisms of this effect are largely unknown. In this study, a method to model this effect was proposed. A characteristic dimensionless number for connecting the bulk spray properties and the microscopic emulsion droplet properties was defined as the ratio between the emulsion recovery time and the spray atomization time. This study will help in the design of agricultural spray nozzles and the optimization of anti-drift spray additives.

References

1.
Miller
,
P. C. H.
and
Butler Ellis
,
M. C.
, “
Effects of Formulation on Spray Nozzle Performances for Applications from Ground-Based Sprayers
,”
Crop Prot.
, Vol.
19
, No.
8
,
2000
, pp.
609
615
. https://doi.org/10.1016/S0261-2194(00)00080-6
2.
Hewitt
,
A. J.
, “
Spray Optimization Through Application and Liquid Physical Property Variables-I
,”
Environmentalist
, Vol.
28
,
2008
, pp.
25
30
. https://doi.org/10.1007/s10669-007-9044-5
3.
Hewitt
,
A. J.
, “
Effect of Tank Mix and Adjuvants on Spray Drift
,”
Proc Fifth International Symposium Adjuvants for Agrochemicals, Vol. I
, Memphis, TN
1998
,
P.
McMullan
, pp.
451
462
.
4.
Butler Ellis
,
M. C.
,
Tuck
,
C. R.
, and
Miller
,
P. C. H.
, “
How Surface Tension of Surfactant Solutions Influences the Characteristics of Sprays Produced by Hydraulic Nozzles Used for Pesticide Application
,”
Colloids Surf., A
 0927-7757, Vol.
180
,
2001
, pp.
267
276
. https://doi.org/10.1016/S0927-7757(00)00776-7
5.
Dexter
,
R. W.
, “
Aqueous Spray Compositions
,” U.S. Patent No. 6,214,771 B1 (
2001
).
6.
Rose
,
S. A. H.
,
Hey
,
S. M.
, and
Early
,
J. E.
, “
Process for Preparing and Applying Pesticide or Herbicide Formulation
,” WO Patent Application 2008/101818 A2 (
2008
).
7.
Mun
,
R. P.
,
Young
,
B. W.
, and
Boger
,
D. V.
, “
Atomisation of Dilute Polymer Solutions in Agricultural Spray Nozzles
,”
J. Non-Newtonian Fluid Mech.
 0377-0257, Vol.
83
,
1999
, pp.
163
178
. https://doi.org/10.1016/S0377-0257(98)00135-9
8.
Hewitt
,
A. J.
, “
Drift Control Adjuvants in Spray Applications: Performance and Regulatory Aspects
,”
Proc. Third Latin American Symposium on Agricultural Adjuvants
, Sao Paolo, Brazil,
2003
.
9.
Hermansky
,
C. G.
and
Krause
,
G. F.
, “
Relevant Physical Property Measurements for Adjuvants
,”
Proc. Fourth International Symposium Adjuvants for Agrochemicals
, Melbourne, Australia,
1995
,
R. E.
Gaskin
, ed., pp.
20
26
.
10.
Dexter
,
R. W.
, “
The Effect of Fluid Properties on the Spray Quality from a Flat Fan Nozzle
,”
Pesticide Formulation and Applications System: 20th Volume, ASTM STP 1400
,
A. K.
Viets
,
R. S.
Tann
, and
J. C.
Mueninghoff
, Eds.,
ASTM International
,
West Conshohocken, PA
,
2001
.
11.
Miller
,
P. C. H.
,
Hewitt
,
A. J.
, and
Bagley
,
W. E.
, “
Adjuvant Effects on Spray Characteristics and Drift Potential
,”
Pesticide Formulations and Applications Systems, ASTM-STP, 21st Volume
,
ASTM International
,
West Conshohocken, PA
,
2001
.
12.
Butler Ellis
,
M. C.
,
Tuck
,
C. R.
, and
Miller
,
P. C. H.
, “
Dilute Emulsions and Their Effect on the Breakup of the Liquid Sheet Produced by Flat-Fan Spray Nozzles
,”
Atomization Sprays
 1044-5110, Vol.
9
,
1999
, pp.
385
397
.
13.
Bergeron
,
V.
, “
Designing Intelligent Fluids for Controlling Spray Applications
,”
C. R. Phys.
 1631-0705, Vol.
4
,
2003
, pp.
211
219
. https://doi.org/10.1016/S1631-0705(03)00043-4
14.
Zhu
,
H.
,
Brazee
,
R. D.
,
Reichard
,
D. L.
,
Fox
,
R. D.
,
Krause
,
C. R.
, and
Chapple
,
A. C.
, “
Fluid Velocity and Shear in Elliptic Orifice Spray Nozzles
,”
Atomization Sprays
 1044-5110, Vol.
5
(
3
),
1995
, pp.
343
356
.
15.
Qin
,
K.
,
Tank
,
H.
,
Wilson
,
S. A.
,
Downer
,
B.
,
Liu
,
L.
, “
Controlling Droplet-Size Distribution Using Oil Emulsions in Agricultural Sprays
,”
Atomization Sprays
 1044-5110, Vol.
20
, No.
3
,
2009
, pp.
227
239
.
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