Abstract
In recent years, biodiesel has gained considerable attention because of the increasing concern for the environmental problems associated with the use of fossil fuels. The determination of fuel quality is an issue of great importance to the successful commercialization of biodiesel. According to ASTM and EN standards, the analysis of free and total glycerin, contaminants that can lead to serious engine problems, must be carried out by GC analysis. This work presents an alternative method for identifying and quantifying these major contaminants in biodiesel. EASI(+)-MS has shown to function as a fast and secure method, with little or no sample preparation and no pre-separation.
Issue Section:
Technical Notes
References
1.
Krawczyk
, T.
, “Biodiesel-Alternative Fuel Makes Inroads but Hurdles Remain
,” Inform
, Vol. 7
, 1996
, pp. 801
–829
.2.
Ma
, F.
and Hanna
, M. A.
, “Biodiesel Production: A Review
,” Bioresour. Technol.
, Vol. 70
, 1999
, pp. 1
–15
. https://doi.org/10.1016/S0960-8524(99)00025-53.
Li
, Q.
, Du
, W.
, and Liu
, D.
, “Perspectives of Microbial Oils for Biodiesel Production
,” Appl. Microbiol. Biotechnol.
, Vol. 80
, 2008
, pp. 749
–756
. https://doi.org/10.1007/s00253-008-1625-94.
ASTM D6751-08a,
2008
, “Standard Specification for Biodiesel (B100) Fuel Blend Stock (B100) for Middle Distillate Fuels
,” Annual Book of ASTM Standards
, Vol. 05.03
, ASTM International
, West Conshohocken, PA
.5.
Moser
, B. R.
, “Biodiesel Production, Properties, and Feedstocks
,” In Vitro Cell. Dev. Biol. Plant
, Vol. 45
, 2009
, pp. 229
–266
.6.
The Biodiesel Handbook
G.
Knothe
, J.
Van Gerpen
, and J.
Krahl
, Eds., AOCS
, Urbana
, 2005
.7.
Knothe
, G.
and Steidley
, K. R.
, “Kinematic Viscosity of Biodiesel Fuel Components and Related Compounds: Influence of Compound Structure and Comparison to Petrodiesel Fuel Components
,” Fuel
, Vol. 84
, 2005
, pp. 1059
–1065
. https://doi.org/10.1016/j.fuel.2005.01.0168.
Mittelbach
, M.
, Worgetter
, M.
, Pernkopf
, J.
, and Junek
, H.
, “Diesel Fuel Derived from Vegetable Oils: Preparation and Use of Rape Oil Methyl Ester
,” Energy Agric.
, Vol. 2
, 1983
, pp. 369
–384
. https://doi.org/10.1016/0167-5826(83)90031-19.
EN14214:2008, “
Automotive Fuels—Fatty Acid Methyl Esters (FAME) for Diesel Engines—Requirement Methods. Brussels
,” European Committee for Standardization (CEN), Belgium, 2009
.10.
Resolution ANP No.7,
2008
, “Natural Gas and Biofuels
,” ANP, Brazilian National Agency of Petroleum, http://nxt.anp.gov.br/nxt/gateway.Dll/leg/resolucao_anp/2011/fevereiro/ranp%%207%20%202011.xml (Last accessed March 3, 2008).11.
Freedman
, B.
, Kwolek
, W. F.
, and Pryde
, E. H.
, “Quantitation in the Analysis of Transesterified Soybean Oil by Capillary Gas Chromatography
,” J. Am. Oil Chem. Soc.
, Vol. 63
, 1986
, pp. 1370
–1375
. https://doi.org/10.1007/BF0267960512.
Plank
, C.
and Lorbeer
, E.
, “Simultaneous Determination of Glycerol, and Mono-, Di-, and Triglycerides in Vegetable Oil Methyl Esters by Capillary Gas Chromatography
,” J. Chromatogr.
, Vol. A697
, 1995
, pp. 461
–468
.13.
Foglia
, T. A.
, Jones
, K. C.
, Nuñes
, A.
, Phillips
, J. G.
, and Mittelbach
, M.
, “Comparison of Chromatographic Methods for the Determination of Bound Glycerol in Biodiesel
,” Chromatographia
, Vol. 60
, 2004
, pp. 305
–311
.14.
Knothe
, G.
, “Analytical Methods Used in the Production and Fuel Quality Assessment of Biodiesel
,” Trans. ASAE
, Vol. 44
(2
), 2001
, pp. 193
–200
.15.
Haddad
, R.
, Sparrapan
, R.
, and Eberlin
, M. N.
, “Desorption Sonic Spray Ionization for (High) Voltage-Free Ambient Mass Spectrometry
,” Rapid Commun. Mass Spectrom.
, Vol. 20
, 2006
, pp. 2901
–2905
. https://doi.org/10.1002/rcm.268016.
Haddad
, R.
, Sparrapan
, R.
, Kotiaho
, T.
, and Eberlin
, M. N.
, “Easy Ambient Sonic-Spray Ionization-Membrane Interface Mass Spectrometry for Direct Analysis of Solution Constituents
,” Anal. Chem.
, Vol. 80
, 2008
, pp. 898
–903
. https://doi.org/10.1021/ac701960q17.
Haddad
, R.
, Milagres
, H. M. S.
, Catharino
, R. R.
, and Eberlin
, M. N.
, ” Easy Ambient Sonic-Spray Ionization Mass Spectrometry Combined with Thin-Layer Chromatography
,” Anal. Chem.
, Vol. 80
, 2008
, pp. 2744
–2750
. https://doi.org/10.1021/ac702216q18.
Alberici
, R. M.
, Simas
, R. C.
, Sanvido
, G. B.
, Romão
, W.
, Lalli
, P. M.
, Benassi
, M.
, Cunha
, I. B. S.
, and Eberlin
, M. N.
, “Ambient Mass Spectrometry: Bringing MS into the Real World
,” Anal. Bioanal. Chem.
, Vol. 398
, 2010
, pp. 265
–294
. https://doi.org/10.1007/s00216-010-3808-319.
Glenn
, A. H.
, Galhena
, A. S.
, and Fernandez
, F. M.
, “Ambient Sampling/Ionization Mass Spectrometry: Applications and Current
,” Trends Anal. Chem.
, Vol. 83
, 2011
, pp. 4508
–4538
.20.
Chen
, H.
, Gamez
, G.
, and Zenobi
, R.
, “What Can We Learn from Ambient Ionization Techniques?
” J. Am. Soc. Mass Spectrom.
, Vol. 20
, 2009
, pp. 1947
–1963
. https://doi.org/10.1016/j.jasms.2009.07.02521.
Ifa
, D. R.
, Wu
, C.
, Ouyang
, Z.
, and Cooks
, R. G.
, “Desorption Electrospray Ionization and Other Ambient Ionization Methods: Current Progress and Preview
,” Analyst
, Vol. 135
, 2010
, pp. 669
–681
. https://doi.org/10.1039/b925257f22.
Weston
, D. J.
, “Ambient Ionization Mass Spectrometry: Current Understanding of Mechanistic Theory; Analytical Performance and Applications Areas
,” Analyst
, Vol. 135
, 2010
, pp. 661
–668
. https://doi.org/10.1039/b925579f23.
Hirabayashi
, A.
, Sakairi
, M.
, and Koizumi
, H.
, “Sonic Spray Mass Spectrometry
,” Anal. Chem.
, Vol. 67
, 1995
, pp. 2878
–2882
. https://doi.org/10.1021/ac00113a02324.
Hirabayashi
, A.
, Hirabayashi
, Y.
, Sakairi
, M.
, and Koizumi
, H.
, “Multiply-Charged Ion Formation by Sonic Spray
,” Anal. Rapid Commun. Mass Spectrom.
, Vol. 10
, 1996
, pp. 1703
–1705
. https://doi.org/10.1002/(SICI)1097-0231(199610)10:13<1703::AID-RCM687>3.0.CO;2-J25.
Abdelnur
, P. V.
, Eberlin
, L. S.
, de Sá
, G. F.
, Souza
, V.
, and Eberlin
, M. N.
, “Single-Shot Biodiesel Analysis: Nearly Instantaneous Typification and Quality Control Solely by Ambient Mass Spectrometry
,” Anal. Chem.
, Vol. 80
, 2008
, pp. 7882
–7886
. https://doi.org/10.1021/ac801400526.
Eberlin
, L. S.
, Abdelnur
, P. V.
, Passero
, A.
, de Sá
, G. F.
, Daroda
, R. J.
, Souza
, V.
, and Eberlin
, M. N.
, “Analysis of Biodiesel and Biodiesel-Petrodiesel Blends by High Performance Thin Layer Chromatography Combined with Easy Ambient Sonic-Spray Ionization Mass Spectrometry
,” Analyst
, Vol. 134
, 2009
, pp. 1652
–1657
. https://doi.org/10.1039/b817847j27.
Alberici
, R. M.
, Simas
, R. C.
, Souza
, V.
, de Sá
, G. F.
, Daroda
, R. J.
, and Eberlin
, M. N.
, “Analysis of Fuels via Easy Ambient Sonic-Spray Ionization Mass Spectrometry
,” Anal. Chim. Acta
, Vol. 659
, 2010
, pp. 15
–22
. https://doi.org/10.1016/j.aca.2009.11.03328.
Alberici
, R. M.
, Simas
, R. C.
, Abdelnur
, P. V.
, Eberlin
, M. N.
, Souza
, V.
, de Sá
, G. F.
, and Daroda
, R. J.
,” A Highly Effective Antioxidant and Artificial Marker for Biodiesel
,” Energy Fuels
, Vol. 24
, 2010
, pp. 6522
–6526
. https://doi.org/10.1021/ef100968b29.
Alberici
, R. M.
, Souza
, V.
, de Sá
, G. F.
, Daroda
, R. J.
, Morelli
, S. R.
, and Eberlin
, M. N.
, “Used Frying Oil: A Proper Feedstock for Biodiesel Production?
” Bioenergy Res.
2011
(to be published).30.
Simas
,R. C.
, Catharino
, R. R.
, Cunha
, I. B. S.
, Cabral
, E. C.
, Barrera-Arellano
, D.
, Eberlin
, M. N.
, and Alberici
, R. M.
, “Instantaneous Characterization of Vegetable Oils via TAG and FFA Profiles by Easy Ambient Sonic-Spray Ionization Mass Spectrometry
,” Analyst
, Vol. 135
, 2010
, pp. 735
–744
.
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